LrgpV1, Main, Exploration, bibRecord, 001332

Modeling of the rheological behavior of polyethylene/supercritical CO2 solutions

Identifieur interne : 001332 ( Main/Exploration ); précédent : 001331; suivant : 001333

Modeling of the rheological behavior of polyethylene/supercritical CO2 solutions

Auteurs : M. Nobelen [France, Belgique] ; S. Hoppe [France] ; C. Fonteix [France] ; F. Pla [France] ; M. Dupire [Belgique] ; B. Jacques [Belgique]

Source :

Chemical engineering science [ 0009-2509 ] ; 2006.

RBID : Pascal:06-0334164

Descripteurs français

Pascal (Inist)
- Modélisation, Carbone dioxyde, Etat supercritique, Viscosité, Tube capillaire, Presse extrusion double vis, Presse extrusion, Perte charge, Hydrodynamique, Plan expérience, Cisaillement, Ordre 2, Modèle théorique, Loi puissance, Facteur correction, Effet température, Extrusion.

English descriptors

KwdEn :
- Capillary tube, Carbon dioxide, Correction factor, Double screw extruder, Experimental design, Extruder, Extrusion, Hydrodynamics, Modeling, Power law, Pressure drop, Second order, Shear, Supercritical state, Temperature effect, Theoretical model, Viscosity.

Abstract

This paper deals with the modeling of the rheological behavior of polyethylene (PE)/supercritical CO₂ solutions. Melt viscosity measurements were performed using a capillary tube die attached to a twin screw extruder, for different amounts of CO₂ injected into the extruder barrel (from 0 to 4 wt%). The viscosity of the solutions was determined by measuring the pressure drop and the polymer flow rate through the die. A D-optimal experimental design was developed to determine the minimal number of experiments necessary with a minimization of the error on the model coefficients. The experimental results showed that the viscosity of PE/CO₂ solutions depends on shear rate, temperature, pressure, and CO₂ concentration. The pressure in the capillary was modeled by a second order polynomial. A theoretical model based on a power law was proposed to describe the pseudoplastic behavior of PE/CO₂ solutions with different shear rates. Correction factors were included to take into account the effects of temperature, pressure, and CO₂ concentration.

Affiliations:

Links toward previous steps (curation, corpus...)

to stream PascalFrancis, to step Corpus: 000499
to stream PascalFrancis, to step Curation: 000612
to stream PascalFrancis, to step Checkpoint: 000482
to stream Main, to step Merge: 001556
to stream Main, to step Curation: 001332

Le document en format XML

<record><TEI><teiHeader><fileDesc><titleStmt><title xml:lang="en" level="a">Modeling of the rheological behavior of polyethylene/supercritical CO<sub>2</sub>
 solutions</title>
<author><name sortKey="Nobelen, M" sort="Nobelen, M" uniqKey="Nobelen M" first="M." last="Nobelen">M. Nobelen</name>
<affiliation wicri:level="3"><inist:fA14 i1="01"><s1>Laboratoire des Sciences du Génie Chimique, CNRS-ENSIC, 1 rue Grandville, BP 20451</s1>
<s2>54001 Nancy</s2>
<s3>FRA</s3>
<sZ>1 aut.</sZ>
<sZ>2 aut.</sZ>
<sZ>3 aut.</sZ>
<sZ>4 aut.</sZ>
</inist:fA14>
<country>France</country>
<placeName><region type="region" nuts="2">Grand Est</region>
<region type="old region" nuts="2">Lorraine (région)</region>
<settlement type="city">Nancy</settlement>
</placeName>
</affiliation>
<affiliation wicri:level="1"><inist:fA14 i1="02"><s1>Total Petrochemicals Research Feluy, Zone Industrielle C</s1>
<s2>7181 Feluy</s2>
<s3>BEL</s3>
<sZ>1 aut.</sZ>
<sZ>5 aut.</sZ>
<sZ>6 aut.</sZ>
</inist:fA14>
<country>Belgique</country>
<wicri:noRegion>7181 Feluy</wicri:noRegion>
</affiliation>
</author>
<author><name sortKey="Hoppe, S" sort="Hoppe, S" uniqKey="Hoppe S" first="S." last="Hoppe">S. Hoppe</name>
<affiliation wicri:level="3"><inist:fA14 i1="01"><s1>Laboratoire des Sciences du Génie Chimique, CNRS-ENSIC, 1 rue Grandville, BP 20451</s1>
<s2>54001 Nancy</s2>
<s3>FRA</s3>
<sZ>1 aut.</sZ>
<sZ>2 aut.</sZ>
<sZ>3 aut.</sZ>
<sZ>4 aut.</sZ>
</inist:fA14>
<country>France</country>
<placeName><region type="region" nuts="2">Grand Est</region>
<region type="old region" nuts="2">Lorraine (région)</region>
<settlement type="city">Nancy</settlement>
</placeName>
</affiliation>
</author>
<author><name sortKey="Fonteix, C" sort="Fonteix, C" uniqKey="Fonteix C" first="C." last="Fonteix">C. Fonteix</name>
<affiliation wicri:level="3"><inist:fA14 i1="01"><s1>Laboratoire des Sciences du Génie Chimique, CNRS-ENSIC, 1 rue Grandville, BP 20451</s1>
<s2>54001 Nancy</s2>
<s3>FRA</s3>
<sZ>1 aut.</sZ>
<sZ>2 aut.</sZ>
<sZ>3 aut.</sZ>
<sZ>4 aut.</sZ>
</inist:fA14>
<country>France</country>
<placeName><region type="region" nuts="2">Grand Est</region>
<region type="old region" nuts="2">Lorraine (région)</region>
<settlement type="city">Nancy</settlement>
</placeName>
</affiliation>
</author>
<author><name sortKey="Pla, F" sort="Pla, F" uniqKey="Pla F" first="F." last="Pla">F. Pla</name>
<affiliation wicri:level="3"><inist:fA14 i1="01"><s1>Laboratoire des Sciences du Génie Chimique, CNRS-ENSIC, 1 rue Grandville, BP 20451</s1>
<s2>54001 Nancy</s2>
<s3>FRA</s3>
<sZ>1 aut.</sZ>
<sZ>2 aut.</sZ>
<sZ>3 aut.</sZ>
<sZ>4 aut.</sZ>
</inist:fA14>
<country>France</country>
<placeName><region type="region" nuts="2">Grand Est</region>
<region type="old region" nuts="2">Lorraine (région)</region>
<settlement type="city">Nancy</settlement>
</placeName>
</affiliation>
</author>
<author><name sortKey="Dupire, M" sort="Dupire, M" uniqKey="Dupire M" first="M." last="Dupire">M. Dupire</name>
<affiliation wicri:level="1"><inist:fA14 i1="02"><s1>Total Petrochemicals Research Feluy, Zone Industrielle C</s1>
<s2>7181 Feluy</s2>
<s3>BEL</s3>
<sZ>1 aut.</sZ>
<sZ>5 aut.</sZ>
<sZ>6 aut.</sZ>
</inist:fA14>
<country>Belgique</country>
<wicri:noRegion>7181 Feluy</wicri:noRegion>
</affiliation>
</author>
<author><name sortKey="Jacques, B" sort="Jacques, B" uniqKey="Jacques B" first="B." last="Jacques">B. Jacques</name>
<affiliation wicri:level="1"><inist:fA14 i1="02"><s1>Total Petrochemicals Research Feluy, Zone Industrielle C</s1>
<s2>7181 Feluy</s2>
<s3>BEL</s3>
<sZ>1 aut.</sZ>
<sZ>5 aut.</sZ>
<sZ>6 aut.</sZ>
</inist:fA14>
<country>Belgique</country>
<wicri:noRegion>7181 Feluy</wicri:noRegion>
</affiliation>
</author>
</titleStmt>
<publicationStmt><idno type="wicri:source">INIST</idno>
<idno type="inist">06-0334164</idno>
<date when="2006">2006</date>
<idno type="stanalyst">PASCAL 06-0334164 INIST</idno>
<idno type="RBID">Pascal:06-0334164</idno>
<idno type="wicri:Area/PascalFrancis/Corpus">000499</idno>
<idno type="wicri:Area/PascalFrancis/Curation">000612</idno>
<idno type="wicri:Area/PascalFrancis/Checkpoint">000482</idno>
<idno type="wicri:explorRef" wicri:stream="PascalFrancis" wicri:step="Checkpoint">000482</idno>
<idno type="wicri:doubleKey">0009-2509:2006:Nobelen M:modeling:of:the</idno>
<idno type="wicri:Area/Main/Merge">001556</idno>
<idno type="wicri:Area/Main/Curation">001332</idno>
<idno type="wicri:Area/Main/Exploration">001332</idno>
</publicationStmt>
<sourceDesc><biblStruct><analytic><title xml:lang="en" level="a">Modeling of the rheological behavior of polyethylene/supercritical CO<sub>2</sub>
 solutions</title>
<author><name sortKey="Nobelen, M" sort="Nobelen, M" uniqKey="Nobelen M" first="M." last="Nobelen">M. Nobelen</name>
<affiliation wicri:level="3"><inist:fA14 i1="01"><s1>Laboratoire des Sciences du Génie Chimique, CNRS-ENSIC, 1 rue Grandville, BP 20451</s1>
<s2>54001 Nancy</s2>
<s3>FRA</s3>
<sZ>1 aut.</sZ>
<sZ>2 aut.</sZ>
<sZ>3 aut.</sZ>
<sZ>4 aut.</sZ>
</inist:fA14>
<country>France</country>
<placeName><region type="region" nuts="2">Grand Est</region>
<region type="old region" nuts="2">Lorraine (région)</region>
<settlement type="city">Nancy</settlement>
</placeName>
</affiliation>
<affiliation wicri:level="1"><inist:fA14 i1="02"><s1>Total Petrochemicals Research Feluy, Zone Industrielle C</s1>
<s2>7181 Feluy</s2>
<s3>BEL</s3>
<sZ>1 aut.</sZ>
<sZ>5 aut.</sZ>
<sZ>6 aut.</sZ>
</inist:fA14>
<country>Belgique</country>
<wicri:noRegion>7181 Feluy</wicri:noRegion>
</affiliation>
</author>
<author><name sortKey="Hoppe, S" sort="Hoppe, S" uniqKey="Hoppe S" first="S." last="Hoppe">S. Hoppe</name>
<affiliation wicri:level="3"><inist:fA14 i1="01"><s1>Laboratoire des Sciences du Génie Chimique, CNRS-ENSIC, 1 rue Grandville, BP 20451</s1>
<s2>54001 Nancy</s2>
<s3>FRA</s3>
<sZ>1 aut.</sZ>
<sZ>2 aut.</sZ>
<sZ>3 aut.</sZ>
<sZ>4 aut.</sZ>
</inist:fA14>
<country>France</country>
<placeName><region type="region" nuts="2">Grand Est</region>
<region type="old region" nuts="2">Lorraine (région)</region>
<settlement type="city">Nancy</settlement>
</placeName>
</affiliation>
</author>
<author><name sortKey="Fonteix, C" sort="Fonteix, C" uniqKey="Fonteix C" first="C." last="Fonteix">C. Fonteix</name>
<affiliation wicri:level="3"><inist:fA14 i1="01"><s1>Laboratoire des Sciences du Génie Chimique, CNRS-ENSIC, 1 rue Grandville, BP 20451</s1>
<s2>54001 Nancy</s2>
<s3>FRA</s3>
<sZ>1 aut.</sZ>
<sZ>2 aut.</sZ>
<sZ>3 aut.</sZ>
<sZ>4 aut.</sZ>
</inist:fA14>
<country>France</country>
<placeName><region type="region" nuts="2">Grand Est</region>
<region type="old region" nuts="2">Lorraine (région)</region>
<settlement type="city">Nancy</settlement>
</placeName>
</affiliation>
</author>
<author><name sortKey="Pla, F" sort="Pla, F" uniqKey="Pla F" first="F." last="Pla">F. Pla</name>
<affiliation wicri:level="3"><inist:fA14 i1="01"><s1>Laboratoire des Sciences du Génie Chimique, CNRS-ENSIC, 1 rue Grandville, BP 20451</s1>
<s2>54001 Nancy</s2>
<s3>FRA</s3>
<sZ>1 aut.</sZ>
<sZ>2 aut.</sZ>
<sZ>3 aut.</sZ>
<sZ>4 aut.</sZ>
</inist:fA14>
<country>France</country>
<placeName><region type="region" nuts="2">Grand Est</region>
<region type="old region" nuts="2">Lorraine (région)</region>
<settlement type="city">Nancy</settlement>
</placeName>
</affiliation>
</author>
<author><name sortKey="Dupire, M" sort="Dupire, M" uniqKey="Dupire M" first="M." last="Dupire">M. Dupire</name>
<affiliation wicri:level="1"><inist:fA14 i1="02"><s1>Total Petrochemicals Research Feluy, Zone Industrielle C</s1>
<s2>7181 Feluy</s2>
<s3>BEL</s3>
<sZ>1 aut.</sZ>
<sZ>5 aut.</sZ>
<sZ>6 aut.</sZ>
</inist:fA14>
<country>Belgique</country>
<wicri:noRegion>7181 Feluy</wicri:noRegion>
</affiliation>
</author>
<author><name sortKey="Jacques, B" sort="Jacques, B" uniqKey="Jacques B" first="B." last="Jacques">B. Jacques</name>
<affiliation wicri:level="1"><inist:fA14 i1="02"><s1>Total Petrochemicals Research Feluy, Zone Industrielle C</s1>
<s2>7181 Feluy</s2>
<s3>BEL</s3>
<sZ>1 aut.</sZ>
<sZ>5 aut.</sZ>
<sZ>6 aut.</sZ>
</inist:fA14>
<country>Belgique</country>
<wicri:noRegion>7181 Feluy</wicri:noRegion>
</affiliation>
</author>
</analytic>
<series><title level="j" type="main">Chemical engineering science</title>
<title level="j" type="abbreviated">Chem. eng. sci.</title>
<idno type="ISSN">0009-2509</idno>
<imprint><date when="2006">2006</date>
</imprint>
</series>
</biblStruct>
</sourceDesc>
<seriesStmt><title level="j" type="main">Chemical engineering science</title>
<title level="j" type="abbreviated">Chem. eng. sci.</title>
<idno type="ISSN">0009-2509</idno>
</seriesStmt>
</fileDesc>
<profileDesc><textClass><keywords scheme="KwdEn" xml:lang="en"><term>Capillary tube</term>
<term>Carbon dioxide</term>
<term>Correction factor</term>
<term>Double screw extruder</term>
<term>Experimental design</term>
<term>Extruder</term>
<term>Extrusion</term>
<term>Hydrodynamics</term>
<term>Modeling</term>
<term>Power law</term>
<term>Pressure drop</term>
<term>Second order</term>
<term>Shear</term>
<term>Supercritical state</term>
<term>Temperature effect</term>
<term>Theoretical model</term>
<term>Viscosity</term>
</keywords>
<keywords scheme="Pascal" xml:lang="fr"><term>Modélisation</term>
<term>Carbone dioxyde</term>
<term>Etat supercritique</term>
<term>Viscosité</term>
<term>Tube capillaire</term>
<term>Presse extrusion double vis</term>
<term>Presse extrusion</term>
<term>Perte charge</term>
<term>Hydrodynamique</term>
<term>Plan expérience</term>
<term>Cisaillement</term>
<term>Ordre 2</term>
<term>Modèle théorique</term>
<term>Loi puissance</term>
<term>Facteur correction</term>
<term>Effet température</term>
<term>Extrusion</term>
</keywords>
</textClass>
</profileDesc>
</teiHeader>
<front><div type="abstract" xml:lang="en">This paper deals with the modeling of the rheological behavior of polyethylene (PE)/supercritical CO<sub>2</sub>
 solutions. Melt viscosity measurements were performed using a capillary tube die attached to a twin screw extruder, for different amounts of CO<sub>2</sub>
 injected into the extruder barrel (from 0 to 4 wt%). The viscosity of the solutions was determined by measuring the pressure drop and the polymer flow rate through the die. A D-optimal experimental design was developed to determine the minimal number of experiments necessary with a minimization of the error on the model coefficients. The experimental results showed that the viscosity of PE/CO<sub>2</sub>
 solutions depends on shear rate, temperature, pressure, and CO<sub>2</sub>
 concentration. The pressure in the capillary was modeled by a second order polynomial. A theoretical model based on a power law was proposed to describe the pseudoplastic behavior of PE/CO<sub>2</sub>
 solutions with different shear rates. Correction factors were included to take into account the effects of temperature, pressure, and CO<sub>2</sub>
 concentration.</div>
</front>
</TEI>
<affiliations><list><country><li>Belgique</li>
<li>France</li>
</country>
<region><li>Grand Est</li>
<li>Lorraine (région)</li>
</region>
<settlement><li>Nancy</li>
</settlement>
</list>
<tree><country name="France"><region name="Grand Est"><name sortKey="Nobelen, M" sort="Nobelen, M" uniqKey="Nobelen M" first="M." last="Nobelen">M. Nobelen</name>
</region>
<name sortKey="Fonteix, C" sort="Fonteix, C" uniqKey="Fonteix C" first="C." last="Fonteix">C. Fonteix</name>
<name sortKey="Hoppe, S" sort="Hoppe, S" uniqKey="Hoppe S" first="S." last="Hoppe">S. Hoppe</name>
<name sortKey="Pla, F" sort="Pla, F" uniqKey="Pla F" first="F." last="Pla">F. Pla</name>
</country>
<country name="Belgique"><noRegion><name sortKey="Nobelen, M" sort="Nobelen, M" uniqKey="Nobelen M" first="M." last="Nobelen">M. Nobelen</name>
</noRegion>
<name sortKey="Dupire, M" sort="Dupire, M" uniqKey="Dupire M" first="M." last="Dupire">M. Dupire</name>
<name sortKey="Jacques, B" sort="Jacques, B" uniqKey="Jacques B" first="B." last="Jacques">B. Jacques</name>
</country>
</tree>
</affiliations>
</record>

Pour manipuler ce document sous Unix (Dilib)

EXPLOR_STEP=$WICRI_ROOT/Wicri/Lorraine/explor/LrgpV1/Data/Main/Exploration

HfdSelect -h $EXPLOR_STEP/biblio.hfd -nk 001332 | SxmlIndent | more

HfdSelect -h $EXPLOR_AREA/Data/Main/Exploration/biblio.hfd -nk 001332 | SxmlIndent | more

Pour mettre un lien sur cette page dans le réseau Wicri

{{Explor lien
   |wiki=    Wicri/Lorraine
   |area=    LrgpV1
   |flux=    Main
   |étape=   Exploration
   |type=    RBID
   |clé=     Pascal:06-0334164
   |texte=   Modeling of the rheological behavior of polyethylene/supercritical CO2 solutions
}}

This area was generated with Dilib version V0.6.32.
Data generation: Sat Nov 11 15:47:48 2017. Site generation: Wed Mar 6 23:31:34 2024

	Serveur d'exploration sur le LRGP
	Attention, ce site est en cours de développement ! Attention, site généré par des moyens informatiques à partir de corpus bruts. Les informations ne sont donc pas validées.

Serveur d'exploration sur le LRGP

Modeling of the rheological behavior of polyethylene/supercritical CO2 solutions

Modeling of the rheological behavior of polyethylene/supercritical CO2 solutions

Source :

Descripteurs français

English descriptors

Abstract

Links toward previous steps (curation, corpus...)

Le document en format XML

Pour manipuler ce document sous Unix (Dilib)

Pour mettre un lien sur cette page dans le réseau Wicri